Di-chlorido-(pyridine-κ)[2,3,5,6-tetra-kis-(pyridin-2-yl)pyrazine-κ , , ]nickel(II).

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Chonnam National University, School of Chemical Engineering, Research Institute of Catalysis, Gwangju, Republic of Korea.

Published: February 2021

In the title complex, [NiCl(CHN)(CHN)], the Ni ion is six-coordinated in a distorted octa-hedral coordination environment defined by three N atoms of the tridentate 2,3,5,6-tetra-2-pyridyl-pyrazine ligand, one N atom of the pyridine ligand and two Cl anions, with the latter being mutually . The complex is disposed about a twofold rotation axis along the axis. The complex molecules are connected in the crystal C-H⋯Cl, C-H⋯N and π-π [closest inter-centroid separation = 3.7446 (14) Å between pyridyl rings].

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Source
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC9462313PMC
http://dx.doi.org/10.1107/S2414314621000948DOI Listing

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