Bis[2-(2-hy-droxy-phen-yl)-1-benzimidazol-3-ium] chloranilate.

IUCrdata

Department of Chemistry, Faculty of Science, Okayama University, Okayama 700-8530, Japan.

Published: November 2021

In the crystal of the title mol-ecular salt {systematic name: bis-[2-(2-hy-droxy-phen-yl)-1-benzimidazol-3-ium] 2,5-di-chloro-3,6-dioxo-cyclo-hexa-1,4-diene-1,4-diolate}, 2CHNO·CClO , the chloranilate anion is located on an inversion centre, so that the asymmetric unit contains one cation and one half of the chloranilate anion. In the crystal, the cation and the anion are connected by a bifurcated N-H⋯(O,O) hydrogen bond, forming a 2:1 unit. The units are linked into a layer lying parallel to (01) O-H⋯O and N-H⋯Cl hydrogen bonds. Between the layers, a C-Cl⋯π inter-action is observed.

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Source
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC9462293PMC
http://dx.doi.org/10.1107/S2414314621011500DOI Listing

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