Emission characteristics and light absorption apportionment of carbonaceous aerosols: A tunnel test conducted in an urban with fully enclosed use of E10 petrol.

To reduce the heavy dependence on petroleum, bioethanol has been increasingly employed as an alternative and sustainable transportation fuel. However, the characteristics of black carbon (BC) emissions from E10 petrol vehicles (i.e., ethanol-gasoline containing 10% ethanol) are still unclear, especially under real driving conditions. Here, a tunnel test was conducted during a cold winter. This tunnel was characterized by heavy traffic comprising more than 98% E10-fueled gasoline vehicles (GVs). Real-time BC concentrations, traffic parameters and meteorological conditions were recorded during the sampling campaign. The average BC concentration inside the tunnel (10.94 ± 5.02 μg m) was almost twice the background concentration. Based on aethalometer AE33 in situ measurements and the minimum R-squared (MRS) method, real-time aerosol light absorption was apportioned. The light absorption proportions of BC, primary brown carbon (BrC) and secondary brown carbon (BrC) were 79.86%, 2.78% and 17.36%, respectively, at 370 nm. The BC emission factor (EF) of the E10-fueled vehicles was 1.09 ± 0.49 mg km·veh and 15.24 ± 6.85 mg·(kg fuel), lower than those of traditional gasoline fueled vehicles in previous studies. This study can support the compilation of vehicular BC emission inventories, provide recommendations for biofuel policies and contribute to comprehensively understanding the climatic impact of E10 petrol.