Rapeseed cultivation is a novel approach to safely utilizing lead (Pb) contaminated farmland. However, the mechanism of Pb absorption in seeds remains uncertain. A field experiment was conducted to explore this mechanism with two contrasting treatments: rapeseed exposed to atmospheric deposition and non-exposed treatment. Non-exposed treatment ultimately decreased Pb content in leaf, silique, and seed by 46.7%, 53.7%, and 53.6%, respectively. Sub-microstructure analysis further confirmed that rapeseed leaves and siliques could directly absorb atmospheric Pb. In addition, Pb isotope analysis indicates that atmospheric deposition is the primary source of silique and seed Pb. The root and silique organs had relative Pb contributions of 28.0% and 72.0%, respectively, to seed. Thus, the direct absorption of atmospheric Pb by siliques during the filling stage was found to be the leading cause of seed Pb pollution.
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http://dx.doi.org/10.1016/j.jhazmat.2022.130284 | DOI Listing |
J Am Chem Soc
January 2025
Radiation Laboratory, University of Notre Dame, Notre Dame, Indiana 46556, United States.
Modulation of singlet and triplet energy transfer from excited semiconductor nanocrystals to attached dye molecules remains an important criterion for the design of light-harvesting assemblies. Whereas one can consider the selection of donor and acceptor with favorable energetics, spectral overlap, and kinetics of energy transfer as a means to direct the singlet and triplet energy transfer pathways, it is not obvious how to control the singlet and triplet characteristics of the donor semiconductor nanocrystal itself. By doping CsPb(ClBr) nanocrystals with Mn, we have now succeeded in increasing the triplet characteristics of semiconductor nanocrystals.
View Article and Find Full Text PDFNat Mater
January 2025
Leiden Institute of Chemistry, Leiden University, Leiden, The Netherlands.
Cathodic corrosion is an electrochemical phenomenon that etches metals at moderately negative potentials. Although cathodic corrosion probably occurs by forming a metal-containing anion, such intermediate species have not yet been observed. Here, aiming to resolve this long-standing debate, our work provides such evidence through X-ray absorption spectroscopy.
View Article and Find Full Text PDFInt J Biol Macromol
January 2025
Department of Oral and Maxillofacial Surgery, School and Hospital of Stomatology, Cheeloo College of Medicine, Shandong University & Shandong Key Laboratory of Oral Tissue Regeneration & Shandong Engineering Research Center of Dental Materials and Oral Tissue Regeneration & Shandong Provincial Clinical Research Center for Oral Diseases, Ji'nan 250012, China. Electronic address:
Dry socket, a common painful complication after tooth extraction, is typically caused by improper blood clot formation or its premature dislodgement, often exacerbated by bacterial infections. Traditional gelatin sponges, widely used as clinical fillers, provide favorable biocompatibility and hemostatic support but suffer from suboptimal hemostatic efficiency, lack of antimicrobial properties, and insufficient anticoagulant factors, which increase the risk of dry socket. Addressing these limitations, a novel tannic acid cross-linked gelatin sponge has been developed using directional lyophilization.
View Article and Find Full Text PDFSpectrochim Acta A Mol Biomol Spectrosc
December 2024
Department of Biomedical Engineering, Faculty of Engineering, Universiti Malaya, Federal Territory of Kuala Lumpur, Kuala Lumpur 50603 Malaysia.
Light-matter interaction has been profoundly studied for sample material classification. However, the optical classification of the sample through the polarized light-matter interaction remains underexplored. It is limited to the measurement of intensity instead of the angle of polarized light (AOP) for its degree of polarization.
View Article and Find Full Text PDFAdv Exp Med Biol
January 2025
Department of Optometry, University of Benin, Benin City, Nigeria.
Contact lenses have become integral tools in the realm of ocular therapeutics, extending beyond their primary function of refractive correction to encompass a diverse array of therapeutic applications. This review explores the evolving role of contact lenses in managing various ocular conditions, highlighting their efficacy in enhancing patient outcomes. Initially developed to correct refractive errors, contact lenses now serve as effective vehicles for delivering medications directly to the ocular surface, offering targeted treatment for conditions such as dry eye syndrome and corneal ulcers.
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