The NIST REFPROP software program is a powerful tool for calculating thermophysical properties of industrially important fluids, and this manuscript describes the models implemented in, and features of, this software. REFPROP implements the most accurate models available for selected pure fluids and their mixtures that are valid over the entire fluid range including gas, liquid, and supercritical states, with the goal of uncertainties approaching the level of the underlying experimental data. The equations of state for thermodynamic properties are primarily of the Helmholtz energy form; a variety of models are implemented for the transport properties. We document the models for the 147 fluids included in the current version. A graphical user interface generates tables and provides extensive plotting capabilities. Properties can also be accessed through third-party apps or user-written code via the core property subroutines compiled into a shared library. REFPROP disseminates international standards in both the natural gas and refrigeration industries, as well as standards for water/steam.
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http://dx.doi.org/10.1021/acs.iecr.2c01427 | DOI Listing |
Ind Eng Chem Res
October 2024
Applied Thermodynamics, Chemnitz University of Technology, Chemnitz 09107, Germany.
J Chem Theory Comput
January 2024
Engineering Thermodynamics, Process and Energy Department, Faculty of Mechanical, Maritime and Materials Engineering, Delft University of Technology, 2628 CB Delft, The Netherlands.
Thermodynamic factors for diffusion connect the Fick and Maxwell-Stefan diffusion coefficients used to quantify mass transfer. Activity coefficient models or equations of state can be fitted to experimental or simulation data, from which thermodynamic factors can be obtained by differentiation. The accuracy of thermodynamic factors determined using indirect routes is dictated by the specific choice of an activity coefficient model or an equation of state.
View Article and Find Full Text PDFJ Chem Eng Data
July 2023
National Institute of Standards and Technology, Material Measurement Laboratory, Applied Chemicals and Materials Division, 325 Broadway, Boulder, CO 80305-3328, U.S.A.
The pressure-density-temperature-composition ( ) data of binary refrigerant mixtures containing R-32 (difluoromethane), R-152a (1,1-difluoroethane), R-227ea (1,1,1,2,3,3,3-heptafluoropropane), R-1234yf (2,3,3,3-tetrafluoropropene), and R-1234ze(E) (-1,3,3,3-tetrafluoropropene) were measured in both the vapor and liquid phases using a two-sinker, magnetic-suspension densimeter. The specific samples in this study comprised two compositions of approximately (0.3/0.
View Article and Find Full Text PDFJ Chem Eng Data
July 2023
National Institute of Standards and Technology, Material Measurement Laboratory, Applied Chemicals and Materials Division, 325 Broadway, Boulder, CO 80305-3328, U.S.A.
The pressure-density-temperature-composition (---) data of binary refrigerant mixtures containing R-134a (1,1,1,2-tetrafluoroethane), R-1234yf (2,3,3,3-tetrafluoropropene), and R-1234ze(E) (-1,3,3,3-tetrafluoropropene) were measured in both the vapor and liquid phases using a two-sinker, magnetic-suspension densimeter. The specific samples in this study comprised two compositions of approximately (0.3/0.
View Article and Find Full Text PDFInd Eng Chem Res
October 2022
Applied Chemicals and Materials Division, National Institute of Standards and Technology, 325 Broadway, Mailstop 647.08, Boulder, Colorado 80305, United States.
The NIST REFPROP software program is a powerful tool for calculating thermophysical properties of industrially important fluids, and this manuscript describes the models implemented in, and features of, this software. REFPROP implements the most accurate models available for selected pure fluids and their mixtures that are valid over the entire fluid range including gas, liquid, and supercritical states, with the goal of uncertainties approaching the level of the underlying experimental data. The equations of state for thermodynamic properties are primarily of the Helmholtz energy form; a variety of models are implemented for the transport properties.
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