Rapid fabrication of the Au hexagonal cone arrays for SERS applications.

Spectrochim Acta A Mol Biomol Spectrosc

School of Science, Nantong University, No.9, Seyuan Road, Nantong, Jiangsu 226019, PR China. Electronic address:

Published: February 2023

This study performed trace detection using surface-enhanced Raman scattering (SERS) on Au hexagonal cone arrays (Au-HCAs). Uniform porous anodized aluminum oxide (AAO) templates were used, and an Ag film with a cone cavity was prepared using a thermal deposition technique. Next, a series of homogeneous Au-HCAs were prepared controllably via electrodeposition growth technology. The prepared Au-HCAs were used as SERS substrates, and according to the experimental results, the optimal electrodeposition time is 600 s. At this time, Au-HCAs had the highest SERS activity. The detection limit of R6G was 10 M, exhibiting high reproducibility and high uniformity at 10 M, indicating that Au-HCAs had good stability. Moreover, a good linear correlation between the Raman intensity and the molecular concentration endowed Au-HCAs with good quantitative analysis ability. Therefore, the Au-HCAs exhibited great potential for qualitative and quantitative detection.

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http://dx.doi.org/10.1016/j.saa.2022.121969DOI Listing

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