Fluorescence Excitation and Dispersed Fluorescence Spectra of the 1-Hydronaphthyl Radical (1-CH) in Solid -Hydrogen.

Matrix isolation spectroscopy with -hydrogen (-H) has previously been employed to record IR absorption spectra of hydrogenated and protonated polycyclic aromatic hydrocarbons (PAHs), prospective carriers of unidentified infrared and diffuse interstellar bands. Despite the promising prospects of -H as matrix host, especially the rather weak interaction with the guest molecules and the resulting small matrix shifts, -H matrix isolation spectroscopy has rarely been applied to study electronic transitions of guest molecules. Here, we present the dispersed fluorescence and fluorescence excitation spectrum of the 1-hydronaphthyl radical (1-CH) isolated in solid -H. We observed a strong 0 band associated with the electronic transition to the first excited electronic state at 18881 cm, red-shifted by ∼68 cm relative to a value reported for jet-cooled 1-CH. From a comparison of our experimental results to simulated vibrationally resolved electronic absorption and emission spectra computed on the basis of (TD-)DFT geometry optimizations and scaled harmonic vibration calculations using the FCclasses code, we derived assignments for observed vibronic transitions. The dispersed fluorescence spectrum of 1-CH is new; it complements the infrared spectrum and identified many vibrational modes unidentifiable with infrared. The excitation spectrum covers a much wider spectral range than previous reports. We compare the excitation spectrum in solid -H to the reported electronic absorption spectrum of jet-cooled gaseous 1-CH and that of 1-CH isolated in solid Ne to assess the influence of -H as a matrix host on the electronic transition of 1-CH and discuss a potential contribution of 1-CH to the diffuse interstellar bands.