A cooperative Cu/Pd-catalysed borylallenylation of 2-trifluoromethyl-1,3-enynes with propargylic carbonates under mild reaction conditions was developed. This method provides facile and efficient access to conjugated bisallenes with a broad range of functional groups. Both aromatic and aliphatic 1,3-enynes can be utilized in this transformation to give the corresponding multi-substituted conjugated bisallenes.
Download full-text PDF |
Source |
|---|---|
| http://dx.doi.org/10.1039/d2cc03745a | DOI Listing |
Publication Analysis
Top Keywords
conjugated bisallenes
12
cooperative cu/pd-catalysed
8
cu/pd-catalysed borylallenylation
8
borylallenylation 2-trifluoromethyl-13-enynes
8
synthesis conjugated
4
bisallenes cooperative
4
2-trifluoromethyl-13-enynes cooperative
4
2-trifluoromethyl-13-enynes propargylic
4
propargylic carbonates
4
carbonates mild
4
Similar Publications
Want AI Summaries of new PubMed Abstracts delivered to your In-box?
Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!