Two-Dimensional Basalt/Ni Microflakes with Uniform and Compact Nanolayers for Optimized Microwave Absorption Performance.

It has been accepted that the uniform distribution of magnetic metal particles is beneficial to microwave absorption, while why the homogeneous magnetic particles on the dielectric substrate improve the electromagnetic loss is still unclear. Herein, metal Ni nanoparticles, two-dimensional (2D) basalt/scattered Ni, and basalt/uniform Ni microflakes are obtained through a pretreatment and electroless deposition process. In comparison to Ni nanoparticles and basalt/scattered Ni, the basalt/Ni microflakes with largely uniform and compact Ni nanolayers on basalt, breaking the percolation limit, are favorable for enhanced electromagnetic attenuation. The Ni nanolayers are convenient for construction of a microscale conductive net and migration of an electron. The 2D heterostructures constructed by basalt substrates and decorated Ni layers boost multiple scattering absorption and promote interfacial polarization. Meanwhile, exposed Ni does not inhibit magnetic resonance, enabling strong magnetic coupling. Consequently, the basalt/Ni microflakes with uniform Ni nanolayers demonstrate better microwave absorption with a minimum reflection loss of -30 dB and an effective absorption bandwidth of 3 GHz at 1 mm. This work shows that the uniform and compact magnetic metal nanolayers are effective in improving the dielectric loss and magnetic loss simultaneously to achieve the high-performance microwave absorption.