In recent years, elastocaloric cooling has shown great potential as an alternative to vapor-compression refrigeration. However, there is still no existing elastocaloric device that offers fatigue-resistant operation and yet high cooling/heat-pumping performance. Here, we introduce a new design of an elastocaloric regenerator based on compression-loaded Ni-Ti tubes, referred to as a shell-and-tube-like elastocaloric regenerator. Our regenerator design, which can operate in both cooling and heat-pumping modes, enables durable operation and record performance with a maximum temperature span of 31.3 K in heat-pumping mode or maximum heating/cooling powers of more than 60 W, equivalent to 4,400 W/kg of the elastocaloric material (at temperature span of 10 K). In terms of both maximum performance metrics, these results surpass all previously developed caloric (magnetocaloric, electrocaloric, and elastocaloric) devices and demonstrate the enormous potential of compression-loaded elastocaloric regenerators to be used in elastocaloric devices for a wide range of cooling and heat-pumping applications.
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http://dx.doi.org/10.1016/j.joule.2022.08.011 | DOI Listing |
Adv Mater
January 2025
State Key Laboratory for Mechanical Behavior of Materials, Xi'an Jiaotong University, Xi'an, 710049, China.
An elastocaloric thermal battery based on generative learning-designed phase-change alloys is developed to facilitate the efficient recycling of low-temperature waste heat. This battery stores thermal energy as latent heat in a phase-change alloy and releases it on demand through applied stress at ambient temperature. Alloy compositions and corresponding processing parameters, tailored to desired transformation characteristics, are efficiently discovered through a generative learning-enabled inverse design framework, which converts the hand-drawn target heat flow curve into tangible compositional and processing designs.
View Article and Find Full Text PDFPolymers (Basel)
November 2024
School of Microelectronics, Southern University of Science and Technology, Shenzhen 518055, China.
Mechanocaloric cooling/heat pumping with zero carbon emission and high efficiency shows great potential for replacing traditional refrigeration with vapor compression. Mechanocaloric prototypes that are developed using shape memory alloys (SMAs) face the problems of a large driving force and high cost. In this work, we report a low-crystalline thermoplastic polyetherurethane (TPU) elastomer fiber with a low actuation force and good mechanocaloric performance.
View Article and Find Full Text PDFPolymers (Basel)
October 2024
Departament de Física de la Matèria Condensada (FMC), Universitat de Barcelona, Martí i Franquès 1, 08028 Barcelona, Catalonia, Spain.
We study the enhancement of the elastocaloric effect in natural rubber by using forced air convection to favour heat extraction during the elongation stage of a stretching-unstretching cycle. Elastocaloric performance is quantified by means of the adiabatic undercooling that occurs after fast removal of the stress, measured by infrared thermography. To ensure accuracy, spatial averaging on thermal maps of the sample surface is performed since undercooled samples display heterogeneities caused by various factors.
View Article and Find Full Text PDFMaterials (Basel)
September 2024
Key Laboratory for Anisotropy and Texture of Materials (Ministry of Education), School of Materials Science and Engineering, Northeastern University, Shenyang 110819, China.
Superelastic shape memory alloys with an integration of large elastocaloric response and good cyclability are crucially demanded for the advancement of solid-state elastocaloric cooling technology. In this study, we demonstrate a giant elastocaloric effect with improved cyclic stability in a <001> textured polycrystalline (NiMnTi)B alloy developed through directional solidification. It is shown that large adiabatic temperature variation (|Δ|) values more than 15 K are obtained across the temperature range from 283 K to 373 K.
View Article and Find Full Text PDFAdv Mater
November 2024
State Key Laboratory of Medicinal Chemical Biology, Key Laboratory of Functional Polymer Materials, College of Chemistry, Nankai University, 94 Weijin Road, Tianjin, 300071, China.
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