The first example of a cationic cluster-based -lanthanide metal-organic framework (MOF) bearing an asymmetric linker, herein named UOTT-4, has been designed and fully characterized. Compared to its rare-earth (RE) anionic counterpart (RE-UiO-66), UOTT-4 was found to significantly improve the performance towards adsorption of iodine vapour at room temperature, opening avenues for the design of the next-generation cationic porous materials for the beneficial uptake and confinement of target molecules.
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| http://dx.doi.org/10.1039/d2cc03299f | DOI Listing |
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