Estimation of sorption-desorption characteristics of biosorbent of Lantana camara leaves for removal of Pb (II) ions from wastewater.

This study points out the method regarding the removal of Pb (II) ions from water by treatment with Lantana camara leaves' biosorbent (LCLB). The sorption process was investigated by varying different parameters pH, contact time, adsorbent dose, initial metal ion concentration, and temperature. For a 5.00 g sorbent dose and a 45 min of the contact period, a Pb (II) ion solution with an initial metal ion concentration of 10 mg/L resulted in 90.7% maximum elimination at an optimum pH 6 and temperature 298 ± 1.5 K with LCLB. The adsorption process was spontaneous and exothermic. The maximum monolayer adsorption was 3.5 mg/g for Pb (II) sorption using LCLB. Adsorption of Pb (II) ions using LCLB (R > 0.999) followed the pseudo-second-order kinetics. The spectroscopic characterization was done by fourier transform infrared (FT-IR) analysis, while scanning electron microscope (SEM) images were captured for the morphological characterization. Desorption experiments revealed that hydrochloric acid has a strong potential as an eluent for Pb (II) ion desorption. The findings proposed that LCLB can be used as an effectual and cost-effective biosorbent for the expulsion of Pb (II) ions.