This paper proposed ITO/Si/ITO semi-cone-shell chiral complexes on silicon nanocones with broadband CD in the mid-infrared band. The experimental results show that when the deposition angle θ = 45°, the first ITO deposition of t = 100 nm, the second Si deposition of t = 200 nm with the azimuth angle unchanged, and the third ITO deposition of t = 200 nm after rotating the azimuth angle of 60°, the prepared chiral structure has a broadband CD response in the mid-infrared band of 2.5-4 µm. The broadband CD effect is produced by the internal resonance of the three-dimensional open cavity. The cone structure can be regarded as a plurality of planar open resonant rings with different diameters, and these rings resonate at different wavelengths. The experimental results also show that the proposed chiral ITO structure exhibits a better broadband CD response than that of the structure composed of traditional metal Ag. Such a chiral structure provides a new method for the design of CD devices in the mid-infrared band.
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http://dx.doi.org/10.1364/OE.472656 | DOI Listing |
Nanomaterials (Basel)
January 2025
Key Laboratory of Optoelectronic Materials and Devices, Institute of Semiconductors, Chinese Academy of Sciences, Beijing 100083, China.
Antimonide laser diodes, with their high performance above room temperature, exhibit significant potential for widespread applications in the mid-infrared spectral region. However, the laser's performance significantly degrades as the emission wavelength increases, primarily due to severe quantum-well hole leakage and significant non-radiative recombination. In this paper, we put up an active region with a high valence band offset and excellent crystalline quality with high luminescence to improve the laser's performance.
View Article and Find Full Text PDFDalton Trans
January 2025
College of Physics, Central South University, Changsha 410083, China.
Mid-infrared thermal radiation has attracted attention due to its wide range of applications. Compared to the static process of thermal emission, if thermal radiation can be dynamically controlled, it would be more suitable for practical applications. Herein, we designed a controllable thermal emitter based on phase change materials.
View Article and Find Full Text PDFACS Earth Space Chem
January 2025
School of Chemistry, Norwich Research Park, University of East Anglia, Norwich NR4 7TJ, U.K.
2-Cyanoindene is one of the few specific aromatic or polycyclic aromatic hydrocarbon (PAH) molecules positively identified in Taurus molecular cloud-1 (TMC-1), a cold, dense molecular cloud that is considered the nearest star-forming region to Earth. We report cryogenic mid-infrared (550-3200 cm) and visible (16,500-20,000 cm, over the ← electronic transition) spectra of 2-cyanoindene radical cations (2CNI), measured using messenger tagging (He and Ne) photodissociation spectroscopy. The infrared spectra reveal the prominence of anharmonic couplings, particularly over the fingerprint region.
View Article and Find Full Text PDFSci Rep
January 2025
Department of Physics, The American University in Cairo, New Cairo, 11835, Egypt.
Inverse design with topology optimization considers a promising methodology for discovering new optimized photonic structure that enables to break the limitations of the forward or the traditional design especially for the meta-structure. This work presents a high efficiency mid infra-red imaging photonics element along mid infra-red wavelengths band starts from 2 to 5 µm based on silicon nitride optimized material structures. The first two designs are broadband focusing and reflective meta-lens under very high numerical aperture condition (NA = 0.
View Article and Find Full Text PDFAbsolute line strength measurements of hydroperoxyl (HO2) radical in the OO-stretching (ν3) fundamental band have been performed by means of mid-infrared time-resolved dual-comb spectroscopy. By employing two sets of dual-comb spectrometers, high-resolution time-resolved spectra of HO2 and HCl, formed in the photolysis reaction system of Cl2/CH3OH/O2, could be, respectively, measured near 1123 and 3059 cm-1. With kinetic simulations, spectral analysis of both HO2 and HCl, as well as the accurate line strength of the HCl R(9) transition at 3059.
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