A novel hydrogel beads based copper-doped Cerastoderma edule shells@Alginate biocomposite for highly fungicide sorption from aqueous medium.

The engineering of a novel biocomposite based on Cerastoderma edule shells doped with copper and alginate (Ce-Cu@Alg) forming hydrogel beads was used for batch and dynamic adsorption thiabendazole (TBZ) pesticide from water. The prepared biosorbent was analyzed by various characterization techniques such as scanning electron microscopy (SEM), X-ray diffraction analysis (XRD), Brunauer-Emmett-Teller analysis (BET), and energy dispersive spectroscopy (EDS), thermogravimetric and differential analysis (TGA-DTA). The results of the TBZ batch biosorption by Ce-Cu@Alg composite showed that the Langmuir model was the most adequate to describe the adsorption process, with a maximum adsorption capacity value of 21.98 mg/g. Moreover, the adsorption kinetics were adjusted by the pseudo-second-order model. The optimal conditions determined by the RSM approach coupled with the CCD design were 100 ppm of initial TBZ concentration, a Ce-Cu@Alg beads dose of 6 g/L and a contact time of 180 min for maximum removal of 83.42%. On the other hand, the TBZ sorption on a fixed bed of Ce-Cu@Alg beads was effective at high column height, low effluent flow and low solution concentration. The Thomas model was best fitted to the kinetic data. This study shows the possibility of using this new hybrid biocomposite in the industrial sector to treat large effluent volumes.