Corrosion resistance and mechanisms of Nd(NO) and polyvinyl alcohol organic-inorganic hybrid material incorporated MAO coatings on AZ31 Mg alloy.

J Colloid Interface Sci

Corrosion Laboratory for Light Metals, School of Materials Science and Engineering, Shandong University of Science and Technology, Qingdao 266590, China; School of Materials Science and Engineering, Zhengzhou University, Zhengzhou 450002, China; Hubei Key Laboratory of Advanced Technology for Automotive Components, Wuhan University of Technology, Wuhan 430070, China. Electronic address:

Published: January 2023

AI Article Synopsis

  • The study focuses on creating new hybrid coatings made from organic polyvinyl alcohol (PVA) and inorganic neodymium nitrate to protect magnesium alloy from corrosion.
  • Various advanced techniques were used to analyze the coatings' chemical and structural properties, ensuring an effective design.
  • The findings indicate that the coatings enhance corrosion resistance and possess a self-healing ability, making them particularly useful for improving durability in magnesium alloys.

Article Abstract

This work reports the design and preparation of novel organic (polyvinyl alcohol, PVA)-inorganic (neodymium nitrate, Nd(NO)) hybrid coatings on micro-arc oxidation (MAO) coating for magnesium (Mg) alloy corrosion protection. X-ray diffractometer, X-ray photoelectron spectroscopy, fourier transform infrared spectroscopy, field emission scanning electron microscope, Energy Dispersive X-ray spectrometer and surface roughness were applied to characterize the chemical composition and surface morphology of the coatings. The corrosion resistance of the coatings was evaluated by electrochemical and salt spray tests. The results suggested that the formation of PVA-Nd and PVA-Mg complexes promoted the enrichment of Nd on the surface, and thereby improved the sealing quality and compactness of the coating. Interestingly, when the coating was damaged, the Nd ions were transformed to their carbonates and covered the active sites, and thus exhibiting self-healing function. Further, the corrosion resistance of PVA-Nd modified MAO composite coating on AZ31 Mg alloy was improved.

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Source
http://dx.doi.org/10.1016/j.jcis.2022.10.087DOI Listing

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