Charge transfer at finite temperature: The "|Δμ| big is good" principle.

J Chem Phys

Department of Chemistry and Quantum Theory Project, University of Florida, Gainesville, Florida 32611, USA.

Published: October 2022

We show that the "|Δμ| big is good" principle holds at temperatures above absolute zero (the so-called "finite-T regime"). We also provide the first conditions hinting at the validity of this reactivity rule in cases where the chemical reactions involved have different signs in their chemical potential variations.

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http://dx.doi.org/10.1063/5.0107355DOI Listing

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