The optical properties of thin films are generally determined by direct photometric quantities. We show that additional insight into the properties of anisotropic thin films can be obtained by computing the polarization eigenstates and eigenvalues of their Jones matrices. We consider helically structured thin films, which display intriguing optical response, such as the circular Bragg resonance. Using numerical simulations and actual measurements, we show that the eigenvectors are mutually orthogonal in most regions of the wavevector space, except near the circular Bragg and the oblique resonances. Special wavevector values, called exceptional points, are found where the Jones matrix becomes defective and its eigenvectors coalesce. Exceptional points are also found in pairs of wavevector values differing only by a sample rotation by π around the direction normal to the sample; this property is shown to arise from Saxton - de Hoop's reciprocity principle, which applies to lossy materials and contains time reversal symmetry, which only applies to lossless materials, as a special case.
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http://dx.doi.org/10.1364/OE.471972 | DOI Listing |
ACS Appl Mater Interfaces
January 2025
State Key Laboratory of Polymer Physics and Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, P. R. China.
Crystalline organic semiconductors, recognized for their highly ordered structures and high carrier mobility, have emerged as a focal point in the field of high-performance optoelectronic devices. Nevertheless, the intrinsic unipolar properties, characterized by imbalanced hole and electron transport capabilities, have continuously represented a significant challenge in the advancement of high-performance crystalline thin-film organic light-emitting diodes (C-OLEDs). Here, a bipolar solid-solution thin film with a maintained crystal structure has been fabricated using 2-(4-(9H-carbazol-9-yl)phenyl)-1(3,5-difluorophenyl)-1H-phenanthro [9,10-d]imidazole (2FPPICz) and 4-(1-(3,5-difluorophenyl)-1H-imidazo[4,5-][1,10]phenanthrolin-2-yl)-N,N-diphenylaniline (2Fn) via a weak epitaxial growth (WEG) process, exhibiting nearly equivalent hole and electron mobilities (10-10 cm V s).
View Article and Find Full Text PDFLangmuir
January 2025
Gulliver, CNRS, ESPCI Paris, Université PSL, Paris 75005, France.
We experimentally study the formation of surface patterns in grafted hydrogel films of nanometer-to-micrometer thickness during imbibition-driven swelling followed by evaporation-driven shrinking. Creases are known to form at the hydrogel surface during swelling; the wavelength of the creasing pattern is proportional to the initial thickness of the hydrogel film with a logarithmic correction that depends on microscopic properties of the hydrogel. We find that, although the characteristic wavelength of the pattern is determined during swelling, the surface morphology can be significantly influenced by evaporation-induced shrinking.
View Article and Find Full Text PDFMater Horiz
January 2025
College of Material and Chemical Engineering, Zhengzhou University of Light Industry, Zhengzhou, Henan 450002, China.
A new photopolymerizable organic-inorganic (O-I) hybrid sol-gel material, AUP@SiO-184, has been synthesized and utilized as a gate dielectric in flexible organic thin-film transistors (OTFTs). The previously reported three-arm alkoxy-functionalized silane amphiphilic polymer has yielded stable O-I hybrid materials comprising uniformly dispersed nanoparticles in the sol state. In this study, a photosensitizer was introduced, facilitating curing effects under ultraviolet light.
View Article and Find Full Text PDFSmall
January 2025
Wuhan National High Magnetic Field Center and School of Physics, Huazhong University of Science and Technology, Wuhan, 430074, China.
Ferroelectric materials, celebrated for their switchable polarization, have undergone significant evolution since their early discovery in Rochelle salt. Initial challenges, including water solubility and brittleness, are overcome with the development of perovskite ferroelectrics, which enable the creation of stable, high-quality thin films suitable for semiconductor applications. As the demand for miniaturization in nanoelectronics has increased, research has shifted toward low-dimensional materials.
View Article and Find Full Text PDFAdv Sci (Weinh)
January 2025
Department of Materials Science and Engineering, University of Maryland, College Park, MD, 20742, USA.
The optical modulation of ferroelectric polarization constitutes a transformative, non-contact strategy for the precise manipulation of ferroelectric properties, heralding advancements in optically stimulated ferroelectric devices. Despite its potential, progress in this domain is constrained by material limitations and the intricate nature of the underlying mechanisms. Recent studies have achieved efficient regulation of ferroelectric polarization and thermal conductivity in chiral ferroelectric thin films through the application of left- and right-handed circularly polarized light (LCP and RCP).
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