The present study quantified element concentrations and evaluated the removal efficiencies of the Lufkin Wastewater Treatment Plant (LWWTP): a public municipal wastewater treatment plant in East Texas. Macroelements (Na, K, Mg, Ca, Al, Fe, Se, Zn, P, and S) and microelements (Ni, Pb, Mn, Cr, Mo, Cu, Co, V, As, B, Ba) were detected using ICP-OES and ICP-MS. In addition, the anion concentrations (Br, NO, NO, PO, F, Cl, and SO) and their percent removal from the LWWTP were assessed by using ion chromatography. Whereas macroelements in the influent were above the maximum ceiling limits, the total metal concentrations in the effluent were found below the USEPA (below μg/L) guidelines. In general, the removal efficiencies for metals in LWWTP were ≥ 94%. The removal efficiencies of the anions were > 100% (Br), 16.42% (Cl), 78.89% (F), 182.59% (NO), > 100% (NO), 51.81% (PO), and 67.01% (SO). In addition, Pierson correlation coefficients between the anions and cations, and implications for usage and suggested improvements of the treatment plants are proposed.
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http://dx.doi.org/10.1007/s10661-022-10622-7 | DOI Listing |
J Environ Manage
December 2024
Department of Chemistry and Biology "Adolfo Zambelli", University of Salerno, via Giovanni Paolo II 132, 84084, Fisciano, SA, Italy.
This study evaluates the combined use of H₂O₂ and thermally activated S₂O₈⁻ (T-PDS) for the degradation of phenolic compounds (PhOH) in wastewater, aiming to limit or eliminate sludge production. Phenolic compounds are common in industrial effluents, and their effective removal is crucial for reducing environmental impact. The study employs Response Surface Methodology (RSM) and Principal Component Analysis (PCA) to optimise critical variables such as temperature, pH, and oxidant concentrations.
View Article and Find Full Text PDFWater Res
December 2024
Soil Chemistry and Chemical Soil Quality Group, Wageningen University & Research, PO BOX 47, Wageningen 6700 AA, the Netherlands.
Binding of glyphosate (PMG) to metal (hydr)oxides controls its availability and mobility in natural waters and soils, and these minerals are often suggested for the removal of PMG from wastewaters. However, a solid mechanistic and quantitative description of the adsorption behavior and surface speciation on these surfaces is still lacking, while it is essential for understanding PMG behavior in aquatic and terrestrial systems. This study gives new insights through advanced surface complexation modeling of new and previously published adsorption data, supplemented with MO/DFT calculations of the geometry, thermochemistry and theoretical infrared (IR) spectra of the surface complexes.
View Article and Find Full Text PDFEnviron Sci Pollut Res Int
December 2024
Department of Environmental Sciences, Maharshi Dayanand University, Rohtak, 124001, Haryana, India.
Constructed wetlands (CWs) are a cost-effective, efficient, and long-term wastewater treatment solution in various countries. The efficacy and performance of constructed wetlands are greatly influenced by the substrate. Recently, biochar as a substrate, along with sand and gravel in constructed wetlands, has gained importance due to its various physical, chemical, and biological properties.
View Article and Find Full Text PDFEnviron Monit Assess
December 2024
Department of Plant Pathology and Entomology, VIT-School of Agricultural Innovation and Advanced Learning, Vellore Institute of Technology, 632014, Vellore, Tamil Nadu, India.
Contamination by heavy metals (HMs) poses a significant threat to the ecosystem and its associated micro and macroorganisms, leading to ill effects on humans which necessitate the requirement of effective remediation strategies. Microbial remediation leverages the natural metabolic abilities of microbes to overcome heavy metal pollution effectively. Some of the mechanisms that aids in the removal of heavy metals includes bioaccumulation, biosorption, and biomineralization.
View Article and Find Full Text PDFMikrochim Acta
December 2024
Frontier Research Centre, Songshan Lake Materials Laboratory, Dongguan, 523830, Guangdong, China.
Clinical and immunological assays of white blood cells (WBCs) in human peripheral blood are of significance for disease diagnosis and immunological studies. However, separating WBCs from blood with high recovery and high purity remains challenging. In this study, by incorporating a pair of linearly tapered filter arrays, a crossflow filtration-based microfluidic chip was designed and fabricated for separation of WBCs from blood.
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