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Synthesis, crystal structure and Hirshfeld surface analysis of (1-benzimidazol-2-yl)(morpholin-4-yl)methane-thione. | LitMetric

The title compound, CHNOS, was synthesized the Willgerodt-Kindler method. The benzimidozole moiety is essentially planar (r.m.s. deviation = 0.0084 Å). The thio-amide group is inclined by 54.80 (14)° to the benzimidazole ring system. The morpholine ring is disordered over two sets of sites [ratio 0.841 (11):0.159 (11)], with chair conformations for both components. In the crystal, mol-ecules are linked into N-H⋯N hydrogen-bonded chains running parallel to the axis. Hirshfeld surface analysis was used to qu-antify the inter-molecular inter-actions.

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http://www.ncbi.nlm.nih.gov/pmc/articles/PMC9535815PMC
http://dx.doi.org/10.1107/S2056989022008933DOI Listing

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