Molecular Simulation of Electron Traps in Epoxy Resin/Graphene Oxide Nanocomposites.

Polymers (Basel)

State Key Laboratory of Alternate Electrical Power System with Renewable Energy Sources, the Beijing Key Laboratory of High Voltage and EMC, North China Electric Power University, Changping, Beijing 102206, China.

Published: October 2022

Trapped space charges in epoxy composite distort the electric field, which will induce the failure of the insulation system, and nano graphene oxide may inhibit the curing behavior of epoxy resin matrix. This paper analyzes how the two interfaces affect the electron traps of epoxy resin/graphene oxide systems with different nanofiller contents. The electron affinity energy of epoxy resin matrix and nano filler molecules in the epoxy resin/graphene oxide system is calculated based on quantum chemistry. It is found that nano graphene oxide has a strong electron affinity energy and is easier to capture electrons. Then the influence of the interface formed by the epoxy resin matrix and the nano graphene oxide on the electron transfer ability is calculated. The epoxy resin matrix contains the electron transfer ability of interfaces formed by nano graphene oxide and the molecular chain is different from that of unreacted molecules. The results can provide a reference for the modification of epoxy resin/graphene oxide nanocomposites.

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Source
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC9570881PMC
http://dx.doi.org/10.3390/polym14194208DOI Listing

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