Graphene Oxide-Modified Epoxy Asphalt Bond Coats with Enhanced Bonding Properties.

The bonding strength of the bond coat plays an important role in the composite action between the wearing surface and the deck plate of the orthotropic steel deck system. Poor bonding results in the delamination of the wearing surface from the deck plate. Graphene oxide (GO) possesses outstanding mechanical and thermal properties, as well as impressive multifunctional groups, which makes it an ideal reinforcement candidate for polymer matrices. In this study, graphene oxide was used to improve the bonding strength and toughness of the epoxy asphalt bond coat (EABC). The dispersion, hydrophobicity, viscosity-time behavior, phase-separated morphology, dynamic mechanical properties, pull-off strength, shear strength and mechanical performance of GO-modified EABCs were investigated using various techniques. The inclusion of GO improved the hydrophobicity of the unmodified EABC. The viscosity of the unmodified EABC was lowered with the addition of GO during curing. Moreover, the allowable construction time for the modified EABCs was extended with the GO loading. The incorporation of GO enhanced the stiffness of the unmodified EABC in the glassy and rubbery states. However, graphene oxide lowered the glass transition temperature of the asphalt of the unmodified EABC. Confocal microscopy observations revealed that GO was invisible in both the asphalt and epoxy phases of the EABC. The inclusion of GO improved the bonding strength, particularly at 60 °C, and mechanical properties of the unmodified EABC.