Constructed wetlands (CWs) are a promising alternative for conventional methods of wastewater treatment. However, the biggest challenge in wastewater treatment is the improvement of the technology used so that it is possible to remove micropollutants without additional costs. The impact of wastewater treatment in CWs on toxicity towards , and was investigated. The effects of feeding regime (wastewater fed in five batches per week at a batch volume of 1 L, or twice per week at a batch volume of 2.5 L) and the presence of pharmaceuticals (diclofenac and sulfamethoxazole), as well as the presence of plants in CW columns (twelve of the 24 columns that were planted) were analyzed. A reduction in toxicity was observed in all experimental setups. The effluents from constructed wetlands were classified as moderately toxic (average TU for , and was 0.9, 2.5 and 5.5, respectively). The feeding regime of 5 days of feeding/2 days of resting resulted in a positive impact on the ecotoxicological and chemical parameters of wastewater (removal of TOC, N-NH and pharmaceuticals). Extended exposure of to the wastewater containing pharmaceuticals resulted in elevated activity of antioxidant enzymes (catalase and superoxide dismutase) in leaf material.
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http://dx.doi.org/10.3390/ijerph191911859 | DOI Listing |
Environ Monit Assess
January 2025
College of the Environment and Ecology, Xiamen University, Xiamen, 361102, Fujian, China.
Synthetic organic dye such as methylene blue (MB) is non-biodegradable and highly toxic, released from textile wastewater. This work investigates the applicability of Ni@ZnO polymer nanocomposite for MB removal from the wastewater. To understand their differences before and after MB adsorption, composites' surface morphology was characterized by various techniques including scanning electron microscope (SEM), thermogravimetric analysis (TGA), X-ray diffraction (XRD), energy dispersive spectroscopy (EDS), Fourier transformation infrared (FT-IR) and UV-Vis spectrophotometer.
View Article and Find Full Text PDFEnviron Monit Assess
January 2025
Department of Chemistry, Chaudhary Bansi Lal University, Bhiwani, Haryana, 127031, India.
Adsorption seemed like an excellent physicochemical process employed for wastewater treatment. In the last few decades, significant improvements have been made in efficiency and economy to remove contaminants from wastewater using several adsorbents. However, less attention was paid to the regeneration of used adsorbents.
View Article and Find Full Text PDFAngew Chem Int Ed Engl
January 2025
USTC: University of Science and Technology of China, Environmental Science and Engineering, CHINA.
The development of advanced catalysts frequently employs trial-and-error methods and is lack of highly controlled synthesis, resulting in unsatisfactory development efficiency and performance. Here we propose a data-driven prediction coupled with precise synthesis strategy to accelerate the development of single-atom catalysts (SACs) for efficient water purification. The data-driven approach enables the rapid screening and prediction of high-performance SACs from 43 metals-N4 structures comprising transition and main group metal elements, followed by validation and structural modulation for improved performance through a highly controllable hard-template method.
View Article and Find Full Text PDFAngew Chem Int Ed Engl
January 2025
Central China Normal University, College of Chemistry, Luoyu Road 152, 430079, Wuhan, CHINA.
Constructing oriented crystalline covalent organic framework (COF) membranes with controllable thickness for water purification is highly desirable. Herein, we present a simple and universal protocol to prepare high-quality COF membranes on the inner wall of a glass vessel using a diffusion/modulator dual-mediated solid-liquid/vapor interfacial synthesis strategy. By meticulous control of the solvent and temperature, a thin supersaturated spreading liquid layer was formed on the glass wall surface and served as a confined microreactor for incubating crystal nuclei.
View Article and Find Full Text PDFBiotechnol Bioeng
January 2025
Biodesign Swette Center for Environmental Biotechnology, Arizona State University, Tempe, Arizona, USA.
Sub-models representing transformation processes by microorganisms and hydrolases, a one-dimensional (1-D) biofilm, and a bioreactor were integrated to simulate organic-matter fermentation and methane (CH) production in an anaerobic moving bed biofilm reactor (AnMBBR). The integrated models correctly represented all experimental observations and identified mechanisms underlying how and why AnMBBR performance changed when the volumetric loading rate (VLR) of total chemical oxygen demand (TCOD) increased from 3.9 to 19.
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