Here, an α-selective C-H bond functionalization of primary aliphatic alcohols with 1,4-naphthoquinones yielded C-C coupled products driven by blue-LED light under catalyst, metal, base, and reagent-free conditions. In this transformation, cleavage of three C-H bonds (two sp-C-H, one sp-C-H, and one O-H) and four new bonds formed, leading to fluorescent 2-acylated-1,4-naphthohydroquinones.
Download full-text PDF |
Source |
|---|---|
| http://dx.doi.org/10.1021/acs.orglett.2c03066 | DOI Listing |
Publication Analysis
Top Keywords
aliphatic alcohols
8
light-driven carbon-carbon
4
carbon-carbon coupling
4
coupling α-sp-ch
4
α-sp-ch aliphatic
4
alcohols sp-ch
4
sp-ch bond
4
bond 14-naphthoquinones
4
14-naphthoquinones α-selective
4
α-selective c-h
4
Similar Publications
Want AI Summaries of new PubMed Abstracts delivered to your In-box?
Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!