A base-induced synthesis of bicyclic 4-aminopyrimidines by the cycloaddition of three types of nitriles is reported. The scope of the method is demonstrated with 44 examples. Products are found to have luminescence properties and show potential applications as organic luminescent layer materials.
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Three-Component Cycloaddition of Nitriles: Construction of Bicyclic 4-Aminopyrimidines and Their Photophysical Studies.
J Org Chem
November 2022
State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, China.
A base-induced synthesis of bicyclic 4-aminopyrimidines by the cycloaddition of three types of nitriles is reported. The scope of the method is demonstrated with 44 examples. Products are found to have luminescence properties and show potential applications as organic luminescent layer materials.
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