Reline deep eutectic solvent mediated synthesis of lanthanum titanate for heavy metal remediation and photocatalytic degradation.

Toxic heavy metal and dye contamination are potential threats that mutilate the essential triad of life; air, water and soil. Despite commercial applicability and importance, the over accumulation of these noxious toxicants has become a disturbing concern. As a result, their remediation has drawn greater fascination leading to the inexplicable quest for a material which can act as both an adsorbent and as a photocatalyst. The present work highlights a novel solid-state technique assisted with reline (Choline chloride: Urea) deep eutectic solvent for the synthesis of lanthanum titanate. The synthesized material was established with physical characterizations like PXRD, FT-IR, UV-DRS, BET, XPS, HR-SEM and TEM techniques. Further, the ruptured petal-like lanthanum titanate was integrated as an adsorbent for the removal of lead (Pb), arsenic (As) and chromium (Cr) heavy metals. The adsorbent presented increased adsorption efficiencies of 96, 74 and 71% towards Pb, As and Cr respectively. Dependence of the degradation efficiency over concentration, pH, contact time and competitive environments were analyzed and inferred. Furthermore, lanthanum titanate was used for the photocatalytic degradation of reactive black (RB5), red (RR198) and yellow (RY145) dyes. The degradation efficiencies were found to be 68.31, 85.2 and 96.8% for RB5, RR198 and RY145 dyes respectively. Variation in concentration and pH of the dye solutions were examined and reaction kinetics was also proposed. In conclusion, the as synthesized lanthanum titanate is assured to play dual roles as a versatile cost-effective adsorbent for the remediation of heavy metals and as a potential candidate for photocatalytic degradation.