Janus membranes have attracted much attention for switchable oil/water separation because they have opposite wetting behavior on each side. However, it remains a challenge to fabricate Janus membranes with asymmetric wettability from biomass by simple methods. Herein, we prepared a flexible Janus wood (JW) membrane by cutting the natural wood along the longitudinal direction, followed by a facile top-down approach. The hydrophobic lignin was removed from the wood to prepare a highly porous and superhydrophilic wood (SW) with underwater superoleophobicity. Then, one side of the SW was sprayed with a mixture of 1H,1H,2H,2H-perfluorooctyltrichlorosilane/SiO nanoparticles to form a superhydrophobic surface that hardly affected the wettability of the other side. The obtained JW membrane maintains its selective wettability in harsh environments owing to its durability and stability. Furthermore, it has a switchable, high separation efficiency of >99% for both oil-in-water and water-in-oil emulsions, which can be attributed to the unique wettability and hierarchical micro/nano structure of the JW membrane. Notably, the three-dimensional interconnected micro/nanochannels (pits and nanopores) of the JW membrane are beneficial to the size-sieving effect during emulsion separation. At the same time, the layered channels (tracheids and vessels) enable multiple separations. JW membrane is sustainable, inexpensive, stable, and easy to manufacture, providing more implications for the innovation of biomass-based Janus separation materials in industrial wastewater treatment.
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http://dx.doi.org/10.1016/j.jcis.2022.09.109 | DOI Listing |
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