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Reaction between RuCl(PPh) and 1,2-diphenylhydrazine resulted in rearrangement and coordination of -semidine. The product, RuCl(PPh)(κ-NH-1,2-CH-NHPh), was characterized spectroscopically and the molecular structure was conclusively determined using X-ray crystallography. Computational chemistry was employed to probe the energetics surrounding the rearrangement reaction and product.
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