AI Article Synopsis
- - The paper discusses the creation of two axially chiral systems by integrating B centers into binaphthyl derivatives, resulting in new chemical structures.
- - This synthesis involves the combination of azaboroles with binaphthyls, leading to the formation of B-N dative bonds in heteroatom-doped chiral polycyclic aromatic hydrocarbons.
- - The resulting B-N Lewis pairs have enhanced fluorescence properties, which allow for adjustments in their chiroptical behavior in both liquid and solid forms.
Article Abstract
We herein describe the synthesis of two axially chiral systems ( and ) by the incorporation of B centers into binaphthyl derivatives ( and ). Heteroatom-doped chiral polycyclic aromatic hydrocarbons were thus formed by fusion of the azaboroles to binaphthyls with the formation of B-N dative bonds. The resulting B-N Lewis pairs that serve as attractive fluorophores enabled modulation of the chiroptical properties both in solution and in the solid state.
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| http://dx.doi.org/10.1021/acs.inorgchem.2c02875 | DOI Listing |
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