Ultrafast formation of ANFs with kinetic advantage and new insight into the mechanism.

Aramid nanofibers (ANFs) have important applications in many fields, including electrical insulation and battery separators. However, a few limitations seriously restrict the application of ANFs currently, such as low preparation efficiency and the unclear preparation mechanism. To overcome these limitations, the present work proposes a new view-point from the perspective of reaction kinetics. The preparation efficiency was proven to essentially rely on the effective (OH). With a simple pre-treatment, a kinetic advantage was created and the preparation time of ANFs was reduced from multiple hours to 10 minutes, which was a considerable step towards practical applications. Moreover, the resultant ANF membranes still exhibited excellent properties in terms of mechanical strength (tensile strength > 160 MPa), thermal stability, light transmittance, and electrical insulation (above 90 kV mm). This work not only presents an ultrafast method to produce ANFs but also provides new insights into the mechanism that will benefit the subsequent development of ANF-based materials.