Role of Ce concentration on the structural and magnetic properties of functional magnetic oxide particles.

Functional magnetic oxide particles offer exceptional GHz frequency capabilities, which can significantly enhance the utility of communication and signal processing devices. In the present work, we have investigated the structural and magnetic properties of rational multifunctional oxide Y Ce BiFeO particles - a full series with = 0.0, 0.2, 0.4, 0.6, 0.8 and 1 a conventional solid-state route. The X-ray diffraction pattern validated the 3̄ cubic garnet phase in all samples. From Rietveld refinement, it is observed that the ceric oxide (CeO) impurity increases with an increase of Ce concentration, evincing a partial substitution of cerium (Ce) element into the garnet structure. The magnetic oxide particles with Ce concentration = 0.4 showed a better crystallite size, dodecahedral site occupancy and solubility of cerium in the garnet phase. The morphological visualization of random shaped grains in the micrometer range was performed using the scanning electron microscopy (SEM) technique. The static magnetic properties showed that the saturation magnetization ( ) decreases up to 43% and coercivity increases up to 59% with the increase of Ce concentration. The dynamic investigation on these oxide particles exhibits various intriguing and novel properties. Various intrinsic material parameters such as saturation magnetization ( ), gyromagnetic ratio (), Gilbert damping constant () and extrinsic contribution (Δ ) to linewidth were determined from the fitting of resonance field ( ) and field linewidth (Δ ) data. We ascertained that the damping constant increases with the increase of Ce concentration, which can be explained in terms of two magnon scattering and local defects caused by CeO inhomogeneity. The proposed doped garnets can be a potential candidate for high frequency microwave applications and spin-transfer-torque devices.