A decade ago, a statistics-based method was introduced to count the number of atoms from annular dark-field scanning transmission electron microscopy (ADF STEM) images. In the past years, this method was successfully applied to nanocrystals of arbitrary shape, size, and composition (and its high accuracy and precision has been demonstrated). However, the counting results obtained from this statistical framework are so far presented without a visualization of the actual uncertainty about this estimate. In this paper, we present three approaches that can be used to represent counting results together with their statistical error, and discuss which approach is most suited for further use based on simulations and an experimental ADF STEM image.
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http://dx.doi.org/10.1017/S1431927622012284 | DOI Listing |
J Am Chem Soc
December 2024
Department of Chemistry, University of Warwick, Library Road, Coventry CV4 7AL, U.K.
Polymer design requires fine control over syntheses and a thorough understanding of their macromolecular structure. Herein, near-atomic level imaging of polymers is achieved, enabling the precise determination of one of the most important macromolecular characteristics: molecular weight. By judiciously designing and synthesizing different linear metal(loid)-rich homopolymers, subnanoscale polymer imaging is achieved through annular dark field-scanning transmission electron microscopy (ADF-STEM), owing to the incorporation of high atoms in the side chain of the monomeric units.
View Article and Find Full Text PDFDent Mater
January 2025
Dental Research Division, Paulista University, Rua Doutor Bacelar, 1212, Zip Code: 04026-002 Sao Paulo, Brazil.
J Phys Chem C Nanomater Interfaces
October 2024
School of Chemistry, University of Southampton, Southampton SO17 1BJ, U.K.
In this work, we present a method for direct, site-selective growth of tellurium nanowires by electrochemical deposition. The Te nanowires were grown laterally between two specially designed nanoband electrodes across a gap, and over a dielectric material, forming a lateral device structure directly. The resulting wires are crystalline and phase pure, as evidenced by Raman spectroscopy, EDS (energy dispersive X-ray spectroscopy), and ADF-STEM (annular dark field scanning transmission electron microscopy).
View Article and Find Full Text PDFDent Mater
January 2025
Dental Research Division, Paulista University, Rua Doutor Bacelar, 1212, Zip Code: 04026-002 Sao Paulo, Brazil. Electronic address:
Objectives: to assess the cytotoxicity of the following functional monomers used in dental adhesives: 10-Methacryloyloxydecyl dihydrogen phosphate (10-MDP) and glycerol phosphate dimethacrylate (GPDM), and their effect on cytokine release from human dental pulp stem cells (hDPSCs).
Methods: The hDPSCs cells were isolated from the dental pulp of extracted human third molars. The functional monomers, 10-MDP and GPDM, were diluted in dimethyl sulfoxide (DMSO) at concentrations ranging from 1 to 4 mM.
Micron
November 2024
School of Physical Sciences, University of Chinese Academy of Sciences, Beijing, China. Electronic address:
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