Fire suppression systems are known to be impacted with residual, entrained per- and polyfluoroalkyl substances (PFASs) because of historical use of aqueous film forming foam (AFFF) and fluoroprotein foam. Amphiphilic PFASs aggregate at liquid:solid interfaces creating a hydrophobic layer which reduces the effectiveness of water to remove PFAS from layered surfaces. When fire suppression systems are transitioned to fluorine free foam (F3) without appropriate cleaning, residual PFASs associated with the surfaces of the fire suppression system can contaminate the replacement F3. Release of residual PFASs from fire suppression systems into F3 has been documented; however, little is known about the residual PFASs associated with the surfaces of the fire suppression systems. More information is needed to develop methods to appropriately remove PFASs from fire suppression systems to prevent costly and inefficient foam transitioning and preserve the PFAS-free benefit of F3. The objective of this work was to evaluate the distribution and composition of PFASs on hangar piping exposed to PFAS-containing firefighting foam for a prolonged period. Two assessment methods were used: 1) extractions with methanol, water, and a proprietary aqueous organic solvent (Fluoro Fighter™); and 2) direct imaging methods of the surface. Extractions were analyzed with mass spectrometry and combustion ion chromatography. Results indicate pipe in contact with PFAS-containing firefighting foam can amass approximately 10 μg/cm of surface-associated PFAS residual following decades of exposure. Fluoro Fighter demonstrated higher PFAS removal per surface area of pipe than methanol (p = 0.007) or water extraction (p < 0.0001). Scanning electron microscope (SEM) images of the hangar piping reveal deposits suspected to be self-assembled PFAS layers, as evidenced by examination of pipe surfaces using X-ray photoelectron spectroscopy (XPS), which revealed atomic fluorine on the surface of the pipe.
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http://dx.doi.org/10.1016/j.chemosphere.2022.136254 | DOI Listing |
Sci Total Environ
January 2025
University of Kansas, Kansas Biological Survey, 2101 Constant Avenue, Takeru Higuchi Hall, Lawrence, KS 66047, USA; University of Kansas, Ecology & Evolutionary Biology, 1200 Sunnyside Avenue Haworth Hall, Lawrence, KS 66045, USA.
Forty percent of terrestrial ecosystems require recurrent fires driven by feedbacks between fire and plant fuels. The accumulation of fine fuels in these ecosystems play a key role in fire intensity, which alters soil nutrients and shapes soil microbial and plant community responses to fire. Changes to post-fire plant fuel production are well known to feed back to future fires, but post-fire decomposition of new fuels is poorly understood.
View Article and Find Full Text PDFBiomolecules
November 2024
Department of Clinical and Experimental Medicine, University of Foggia, Via Rovelli 50, 71122 Foggia, Italy.
a South American ant species from the Formicidae family (subfamily Myrmicinae), has recently established a stable settlement in Europe, raising public health concerns due to its venomous stings. The venom of is rich in bioactive molecules, particularly piperidine alkaloids such as solenopsin A and peptides (Sol 1-4). These compounds have been implicated in various health applications, including antimicrobial, anti-inflammatory, and antitumour activities.
View Article and Find Full Text PDFEnviron Sci Technol
January 2025
Key Laboratory for Semi-Arid Climate Change of the Ministry of Education, College of Atmospheric Sciences, Lanzhou University, Lanzhou 730000, China.
The record-breaking 2019-2020 Australian wildfires have been primarily linked to climate change and its internal variability. However, the meteorological feedback mechanisms affecting smoke dispersion and wildfire emissions on a synoptic scale remain unclear. This study focused on the largest wildfires occurring between December 25, 2019 and January 10, 2020, under the enhanced subtropical high, when the double peak in wildfire evolution was favored by sustained low humidity and two synchronous increases in temperature and wind.
View Article and Find Full Text PDFCell Discov
January 2025
School of Biomedical Sciences, Li Ka Shing Faculty of Medicine, The University of Hong Kong, Pokfulam, Hong Kong SAR, China.
We investigated a novel cancer immunotherapy strategy that effectively suppresses tumor growth in multiple solid tumor models and significantly extends the lifespan of tumor-bearing mice by introducing pathogen antigens into tumors via mRNA-lipid nanoparticles. The pre-existing immunity against the pathogen antigen can significantly enhance the efficacy of this approach. In mice previously immunized with BNT162b2, an mRNA-based COVID-19 vaccine encoding the spike protein of the SARS-CoV-2 virus, intratumoral injections of the same vaccine efficiently tagged the tumor cells with mRNA-expressed spike protein.
View Article and Find Full Text PDFHist Sci
December 2024
Interdisciplinary Center of Social Sciences, NOVA School of Social Sciences and Humanities, Lisbon, Portugal.
This paper examines the intersection of environmental history and the history of science, specifically the impact of forestry science and fire management on land use and community dynamics in rural Portuguese mountains. It further traces the evolution of fire management from an ancestral rural practice to a scientific concern and the subsequent integration of vernacular knowledge with scientific methods. In the early twentieth century, fire was a common tool in rural Portugal for land clearance, pasture management, and soil enrichment.
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