Pore creation nanoarchitectonics from non-porous metal-organic framework to porous carbon for adsorptive elimination of sulfanilamide and chloroxylenol from aqueous solution.

Three isomeric metal-organic frameworks (MOFs) such as MAF-5, - 6, and - 32 (with the same composition of [Zn(2-ethylimidazole)]) were carbonized and, for the first time, activated further with KOH to prepare highly porous MOF-derived carbons (MDCs). Importantly, MDC-32 derived from non-porous MAF-32 had the highest porosity among the three MDCs although it has the lowest porosity when no KOH activation was done. Adsorption of sulfanilamide and chloroxylenol from water was investigated with the MDCs. Among the MDCs, MDC-32 showed the best adsorptive performance for sulfanilamide and chloroxylenol. Moreover, MDC-32, had the highest adsorption capacity (256 mg/g) for removing sulfanilamide from water, compared with any adsorbent reported so far. Based on the observed adsorption and properties of the adsorbate and adsorbent, π-π and hydrogen bonding interactions, with a slight contribution of repulsive electrostatic interaction, could be suggested as the mechanism for the sulfanilamide adsorption over the MDC-32. Moreover, the MDC-32 could be recycled easily for up to four cycles. It could be suggested that non-porous MOFs can be a good precursor for highly porous MDCs, if activated well using KOH, for example. Finally, MAF-32-derived carbon, MDC-32, might be suggested as a plausible adsorbent to eliminate organics such as sulfanilamide from water.