A hallmark of strongly correlated quantum materials is the rich phase diagram resulting from competing and intertwined phases with nearly degenerate ground-state energies. A well-known example is the copper oxides, in which a charge density wave (CDW) is ordered well above and strongly coupled to the magnetic order to form spin-charge-separated stripes that compete with superconductivity. Recently, such rich phase diagrams have also been shown in correlated topological materials. In 2D kagome lattice metals consisting of corner-sharing triangles, the geometry of the lattice can produce flat bands with localized electrons, non-trivial topology, chiral magnetic order, superconductivity and CDW order. Although CDW has been found in weakly electron-correlated non-magnetic AVSb (A = K, Rb, Cs), it has not yet been observed in correlated magnetic-ordered kagome lattice metals. Here we report the discovery of CDW in the antiferromagnetic (AFM) ordered phase of kagome lattice FeGe (refs. ). The CDW in FeGe occurs at wavevectors identical to that of AVSb (refs. ), enhances the AFM ordered moment and induces an emergent anomalous Hall effect. Our findings suggest that CDW in FeGe arises from the combination of electron-correlations-driven AFM order and van Hove singularities (vHSs)-driven instability possibly associated with a chiral flux phase, in stark contrast to strongly correlated copper oxides and nickelates, in which the CDW precedes or accompanies the magnetic order.
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http://dx.doi.org/10.1038/s41586-022-05034-z | DOI Listing |
Chemistry
January 2025
Indian Institute of Science Education and Research (IISER), Chemistry, Dr. Homi Bhabha Road, Pashan, 411008, Pune, INDIA.
Metal-organic frameworks (MOFs) are a fascinating class of structured materials with diverse functionality originating from the distinctive physicochemical properties. This review focuses on the specific chemical design of geometrically frustrated MOFs along with the origin of the intriguing magnetic properties. We have discussed the arrangement of spin centres (metal and ligand) which are responsible for the unusual magnetic phenomena in MOFs.
View Article and Find Full Text PDFAdv Mater
January 2025
Department of Physics, Pohang University of Science and Technology, 77, Cheongam-ro, Nam-gu, Pohang, 37673, Korea (the Republic of).
Janus materials, a novel class of materials with two faces of different chemical compositions and electronic polarities, offer significant potential for various applications with catalytic reactions, chemical sensing, and optical or electronic responses. A key aspect for such functionalities is face-dependent electronic bipolarity, which is usually limited by the chemical distinction of terminated surfaces and has not been exploited in the semiconducting regime. Here, it is showed that a Janus and Kagome van der Waals (vdW) material NbTeI has ferroelectric-like coherent stacking of the Janus layers and hosts strong electronic bipolar states in the semiconducting regime.
View Article and Find Full Text PDFAngew Chem Int Ed Engl
January 2025
The University of Hong Kong, Department of Chemistry, Pokfulam Road, 999077, Hong Kong, CHINA.
Electrically conductive coordination polymers (ECCPs), particularly those incorporating benzenehexathiol (BHT) ligands, are emerging as a distinctive class of electronic materials with tunable semiconducting and metallic properties. However, the exploration of novel ECCPs with low-symmetry structures and electrical anisotropy remains under development. Here, we report the on-water surface synthesis of a novel ECCP, namely Cu5BHT, which exhibits a low-symmetry structure and unique in-plane electrical anisotropy that differs from the well-known Cu3BHT phase.
View Article and Find Full Text PDFNano Lett
January 2025
State Key Laboratory of Structural Analysis for Industrial Equipment & School of Physics, Dalian University of Technology, Dalian 116024 People's Republic of China.
Nanotechnology
January 2025
Departamento de Física, Universidade Federal do Ceará, Campus do Pici, 60455-900 Fortaleza, Ceará, Brazil.
We investigate the electronic properties of nanoribbons made out of monolayer Lieb, transition, and kagome lattices using the tight-binding model with a generic Hamiltonian. It allows us to map the evolutionary stages of the interconvertibility process between Lieb and kagome nanoribbons by means of only one control parameter. Results for the energy spectra, the density of states, and spatial probability density distributions are discussed for nanoribbons with three types of edges: straight, bearded, and asymmetric.
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