Independently unstable thiocarbonylphosphorane or arsorane ligands SCAR (A = P, As) are observed in the salts [W(η-,-SCAR)(CO)(Tp*)]PF [AR = PCy, PMePh: = 0, 1, 2, AsMePh; Tp* = tris(dimethylpyrazolyl)borate] which arise from the reactions of phosphonio- or arsoniocarbynes [W(≡CAR)(CO)(Tp*)] with sulfur.
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Thiocarbonylphosphorane and arsorane ligands.
Chem Commun (Camb)
October 2022
Research School of Chemistry, Australian National University, Canberra, Australian Capital Territory, ACT 2601, Australia.
Independently unstable thiocarbonylphosphorane or arsorane ligands SCAR (A = P, As) are observed in the salts [W(η-,-SCAR)(CO)(Tp*)]PF [AR = PCy, PMePh: = 0, 1, 2, AsMePh; Tp* = tris(dimethylpyrazolyl)borate] which arise from the reactions of phosphonio- or arsoniocarbynes [W(≡CAR)(CO)(Tp*)] with sulfur.
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