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The aim of this study is to acquire a deeper understanding of the response mechanism that is associated with the formation of CdS thin films. We presented an effective and new hybrid sensitisation technique, which involved the 1-step linker between the related chemical bath deposition (CBD) process and the traditional doping method during CBD for synthesising high-quality, CdS thin films. The mechanism for the combined synthesis of the films is also describes. CdS films were electrostatically bonded to soda-lime glass, causing the formation of the intermediate complexes [Cd(NH)], which aided in the collision of these complexes with a soda-lime glass slide. In the one-step fabrication technique, 3-Mercaptopropionic Acid (MPA) was employed as a second source of sulphur ions and a linker molecule. Optical studies showed that the bandgap ranged between (2.26-2.52) eV. CdS + MPA films exhibited a uniform distribution of spherical molecules based on their morphological properties. After annealing, this approach significantly altered the electrical characteristics of CdS films. The CdS + MPA films displayed the highest carrier concentration whereas the CdS + Ag + MPA films exhibited the lowest resistivity, with a jump of 3 orders of magnitude.
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http://www.ncbi.nlm.nih.gov/pmc/articles/PMC9468032 | PMC |
http://dx.doi.org/10.1038/s41598-022-19340-z | DOI Listing |
Nanoscale Adv
December 2024
Department of Chemical Engineering, University of Manchester Manchester M13 9PL UK
Nanocrystals are widely explored for a range of medical, imaging, sensing, and energy conversion applications. CdS nanocrystals have been reported as excellent photocatalysts, with thin film CdS also highly important in photovoltaic devices. To optimise properties of nanocrystals, control over phase, facet, and morphology are vital.
View Article and Find Full Text PDFHeliyon
November 2024
North South University, Dhaka, 1229, Bangladesh.
Thin-film solar cells are a substitute for more common crystalline silicon solar cells, which consist of thin semiconductor layers. Thin-film materials comprise direct bandgap and can absorb sunlight more efficiently than silicon. In this article, a double-absorber-based thin-film solar cell comprising CZTS/CZTSSe is designed and optimized through numerical simulation.
View Article and Find Full Text PDFIndian J Ophthalmol
December 2024
Department of Oculoplasty, Disha Eye Hospitals Pvt Ltd, Kolkata, West Bengal, India.
Small
November 2024
Anhui Key Laboratory of Magnetic Functional Materials and Device, Photoelectric Conversion Energy Materials and Devices Key Laboratory of Anhui Province, School of Materials Science and Engineering, Anhui University, Hefei, 230601, P. R. China.
Regulating the interfacial electric field to achieve rapid charge transfer is crucial for superior photoelectrochemical water splitting. Herein, the ultra-thin hydrogen-substituted graphdiyne (HsGDY) is precisely assembled on the surface of CdS nanorod array (Cu-CdS-HsGDY) by an in situ polymerization strategy. The strong π-d electron coupling is aroused by the delocalized π electrons of HsGDY and the delocalized d electrons of CdS through the interfacial [S─Cu─C] bonds.
View Article and Find Full Text PDFBeilstein J Nanotechnol
November 2024
Department of Nanoscience and Nanoengineering, Graduate School of Natural and Applied Sciences, Atatürk University, 25240, Erzurum, Turkey.
In this study, we aimed to synthesize new carbon dot structures (CDs) in a single step by using the plant for the first time and to contribute to the studies in the field of diode fabrication by using the new CDs. The CDs were obtained by hydrothermal synthesis, which is commonly used in the literature. TEM and zeta potential measurements were used to determine morphology and sizes of the CDs, and XRD, XPS, and FTIR and micro-Raman spectroscopy were used for structural characterization.
View Article and Find Full Text PDFEnter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!