The template effect of a SiF guest drives the formation of a heteroleptic Fe(II) coordination helicate.

Chem Commun (Camb)

Departament de Química Inorgànica i Orgànica and IN2UB, Universitat de Barcelona, Diagonal 645, 08028 Barcelona, Spain.

Published: September 2022

The anion SiF exerts a strong template effect, driving the exclusive assembly of two different bispyridylpyrazolyl ligands into a triple stranded Fe(II) dinuclear heteroleptic helicate, engendering a new class within the large family of coordination helicates.

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Source
http://dx.doi.org/10.1039/d2cc04559aDOI Listing

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