In this study, characterization of biochar for the efficient removal of cadmium was investigated. Biochar has a specific distribution of functional groups on its surface and has a natural electronegativity. Using carbonate as an olation reagent, the biochar coagulates with the olation reaction products. The maximum removal capacity reached 430.4 mg/g at pH = 4 (Langmuir Fit). Carbonate hydrolyzed on the surface of biochar, Cd in solution undergoes olation with OH and forms specially structured nanochains that are positively charged on the surface. The biochar with electronegativity on the surface coagulates with the cadmium hydroxide nanochains, and the cadmium-containing colloid formed by electrostatic attraction settles rapidly and removed. The biochar's re-flocculation performance was consistent, and the loadings could be changed to effectively remove cadmium while keeping the pH neutral at equilibrium.
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| http://dx.doi.org/10.1016/j.scitotenv.2022.158595 | DOI Listing |
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