Solid nanogenerators often have limited charge transfer due to their low contact area. Liquid-liquid nanogenerators can transfer a charge better than the solid-solid and solid-liquid counterparts. However, the precise manipulation of the liquid morphology remains a challenge because of the fluidity limits of the liquid. In this work, using the surface tension of a droplet to fix its shape, a liquid-liquid triboelectric nanogenerator in Contact-Separation mode is designed using an immiscible aqueous-aqueous interface, achieving a contact surface charge transfer of 129 nC for a single droplet. The configuration is proven to be applicable in humid environments, and the two-phase materials have good biocompatibility and can be used as an effective drug carrier. Therefore, this nanogenerator is useful for designing future implantable devices. Meanwhile, this design also establishes the foundation of aqueous electronics, and additional applications can be achieved using this route.
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http://dx.doi.org/10.1038/s41467-022-33086-2 | DOI Listing |
Mater Horiz
August 2024
Joint Research Center of Medicine, The Affiliated Xiangshan Hospital of Wenzhou Medical University, Ningbo, Zhejiang 315700, China.
Zwitterionic hydrogels are electrically neutral materials with both cationic and anionic groups that impart excellent anti-fouling properties and ion channel orientations. However, pure zwitterionic hydrogels generally exhibit low strength and toughness. In this study, it has been discovered that polymerizable zwitterionic monomers in aqueous solution exhibit a unique liquid-liquid phase separation phenomenon at a high monomer concentration of ≥50 wt%, resulting in pure and commercial zwitterionic hydrogels with high compressive strength (6.
View Article and Find Full Text PDFNanomicro Lett
November 2023
CAS Center for Excellence in Nanoscience, Beijing Institute of Nanoenergy and Nanosystems, Chinese Academy of Sciences, Beijing, 100083, People's Republic of China.
The triboelectric nanogenerator (TENG) can effectively collect energy based on contact electrification (CE) at diverse interfaces, including solid-solid, liquid-solid, liquid-liquid, gas-solid, and gas-liquid. This enables energy harvesting from sources such as water, wind, and sound. In this review, we provide an overview of the coexistence of electron and ion transfer in the CE process.
View Article and Find Full Text PDFAdv Mater
February 2024
School of Materials Science and Engineering, Nanyang Technological University, 50 Nanyang Avenue, Singapore, 639798, Singapore.
Fluid-based triboelectric nanogenerators (FB-TENGs) are at the forefront of promising energy technologies, demonstrating the ability to generate electricity through the dynamic interaction between two dissimilar materials, wherein at least one is a fluidic medium (such as gas or liquid). By capitalizing on the dynamic and continuous properties of fluids and their interface interactions, FB-TENGs exhibit a larger effective contact area and a longer-lasting triboelectric effect in comparison to their solid-based counterparts, thereby affording longer-term energy harvesting and higher-precision self-powered sensors in harsh conditions. In this review, various fluid-based mechanical energy harvesters, including liquid-solid, gas-solid, liquid-liquid, and gas-liquid TENGs, have been systematically summarized.
View Article and Find Full Text PDFNat Commun
September 2022
College of Physics, Qingdao University, 266071, Qingdao, China.
Solid nanogenerators often have limited charge transfer due to their low contact area. Liquid-liquid nanogenerators can transfer a charge better than the solid-solid and solid-liquid counterparts. However, the precise manipulation of the liquid morphology remains a challenge because of the fluidity limits of the liquid.
View Article and Find Full Text PDFAngew Chem Int Ed Engl
August 2022
State Key Laboratory for Modification of Chemical Fibers and Polymer Materials, College of Chemistry, Chemical Engineering and Biotechnology & Center for Advanced Low-dimension Materials, Donghua University, Shanghai, 201620, China.
Thermal stiffening materials that are naturally soft but adaptively self-strengthen upon heat are intriguing for load-bearing and self-protection applications at elevated temperatures. However, to simultaneously achieve high modulus change amplitude and high mechanical strength at the stiffened state remains challenging. Herein, entropy-mediated polymer-mineral cluster interactions are exploited to afford thermal stiffening hydrogels with a record-high storage modulus enhancement of 13 000 times covering a super wide regime from 1.
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