It is generally believed that collisions of particles reduce the self-diffusion coefficient. Here we show that in odd-diffusive systems, which are characterized by diffusion tensors with antisymmetric elements, collisions surprisingly can enhance the self-diffusion. In these systems, due to an inherent curving effect, the motion of particles is facilitated, instead of hindered by collisions leading to a mutual rolling effect. Using a geometric model, we analytically predict the enhancement of the self-diffusion coefficient with increasing density. This counterintuitive behavior is demonstrated in the archetypal odd-diffusive system of Brownian particles under Lorentz force. We validate our findings by many-body Brownian dynamics simulations in dilute systems.
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http://dx.doi.org/10.1103/PhysRevLett.129.090601 | DOI Listing |
Angew Chem Int Ed Engl
December 2024
Department of Chemical Engineering, Tsinghua University, Beijing, China.
ACS Omega
November 2024
School of Chemical Engineering and Technology, Xi'an Jiaotong University, Xi'an 710049, People's Republic of China.
The excellent corrosion resistance of stainless steel primarily relies on the formation of a dense passivation film on its surface. Stress corrosion and hydrogen embrittlement are the primary forms of damage to the stainless steel passivation film, leading to film rupture and subsequent corrosion of the stainless steel substrate. The passivation film exhibits semiconducting properties and typically consists of a bilayer structure with a chromium-rich inner layer and an iron-rich outer layer.
View Article and Find Full Text PDFJ Phys Chem A
November 2024
Walker Department of Mechanical Engineering, The University of Texas at Austin, Austin, Texas 78712, United States.
We introduce an approach to describe the long-time dynamics of multiatomic molecules by modulating the free energy landscape (FEL) to capture dominant features of the energy-barrier crossing dynamics of the all-atom (AA) system. Notably, we establish that the self-diffusion coefficient of coarse-grained (CG) systems can be accurately delineated by enhancing conservative force fields with high-frequency perturbations. Using theoretical arguments, we show that these perturbations do not alter the lower-order distribution functions, thereby preserving the structure of the AA system after coarse-graining.
View Article and Find Full Text PDFChemSusChem
October 2024
Dipartimento di Scienza Applicata e Tecnologia, Politecnico di Torino, Corso Duca degli Abruzzi 24, 10129, Torino, Italy.
Small
December 2024
Department of Chemistry, Shanghai Stomatological Hospital, State Key Laboratory of Molecular Engineering of Polymers, Fudan University, Shanghai, 200433, P. R. China.
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