AI Article Synopsis

  • LaBaCoMoO (LBCM) cathodes, synthesized using a sol-gel method, were tested for their effectiveness in intermediate-temperature solid oxide fuel cells.
  • As molybdenum (Mo) content increased, thermal expansion decreased and conductivity improved, showing a significant impact on performance.
  • The best-performing LBCM cathode (LBCM0.04) exhibited a notable reduction in polarization resistance and a substantial increase in maximum power density at 800 °C compared to the undoped version.

Article Abstract

LaBaCoMoO (LBCM, = 0-0.08) cathodes synthesized by a sol-gel method were evaluated for intermediate-temperature solid oxide fuel cells. The limit of the solid solubility of Mo in LBCM was lower than 0.08. As the content of Mo increased gradually from 0 to 0.06, the thermal expansion coefficient decreased from 20.87 × 10 K to 18.47 × 10 K. The introduction of Mo could increase the conductivity of LBCM, which varied from 464 S cm to 621 S cm at 800 °C. The polarization resistance of the optimal cathode LBCM0.04 in air at 800 °C was 0.036 Ω cm, reduced by a factor of 1.67 when compared with the undoped Mo cathode. The corresponding maximum power density of a single cell based on a YSZ electrolyte improved from 165 mW cm to 248 mW cm at 800 °C.

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http://www.ncbi.nlm.nih.gov/pmc/articles/PMC9456714PMC
http://dx.doi.org/10.3390/ma15175858DOI Listing

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