The nano-biocomposite electrodes composed of carbon nanotube (CNT), polypyrrole (PPy), and -bacteria were investigated for electrochemical supercapacitors. For this purpose, PPy/CNT- was successfully synthesized through oxidative polymerization. The PPy/CNT- electrode exhibited a high specific capacitance of 173 F∙g at the current density of 0.2 A∙g, which is much higher than that (37 F∙g) of CNT. Furthermore, it displayed sufficient stability after 1000 charge/discharge cycles. The CNT, PPy/CNT, and PPy/CNT- composites were characterized by x-ray diffraction, scanning electron microscopy, and surface analyzer (Brunauer-Emmett-Teller, BET). In particular, the pyrrole monomers were easily adsorbed and polymerized on the surface of CNT materials, as well as bacteria enhanced the surface area and porous structure of the PPy/CNT- composite electrode resulting in high performance of devices.
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http://dx.doi.org/10.3390/ma15175804 | DOI Listing |
Nanoscale
December 2024
State Key Laboratory of Silicate Materials for Architectures, Wuhan University of Technology, Wuhan 430070, P. R. China.
Sensors (Basel)
March 2024
Department of Bioengineering, Erik Johnsson School of Engineering & Computer Science, University of Texas at Dallas, Richardson, TX 75080, USA.
This study aims to develop a microelectrode array-based neural probe that can record dopamine activity with high stability and sensitivity. To mimic the high stability of the gold standard method (carbon fiber electrodes), the microfabricated platinum microelectrode is coated with carbon-based nanomaterials. Carboxyl-functionalized multi-walled carbon nanotubes (COOH-MWCNTs) and carbon quantum dots (CQDs) were selected for this purpose, while a conductive polymer like poly (3-4-ethylene dioxythiophene) (PEDOT) or polypyrrole (PPy) serves as a stable interface between the platinum of the electrode and the carbon-based nanomaterials through a co-electrodeposition process.
View Article and Find Full Text PDFMembranes (Basel)
June 2023
Departamento de Ingeniería Química, Facultad de Ingeniería, Universidad de Concepción, Edmundo Larenas 219, Concepción 4070409, Chile.
Modification of thin-film composite (TFC) nanofiltration (NF) membranes to increase permeability and improve separation performance remains a significant challenge for water scarcity. This study aimed to enhance the permeability and selectivity of two commercial polyamide (PA) NF membranes, NF90 and NF270, by modifying them with carbon nanotubes (CNTs) using microwave (MW)-assisted in-situ growth. The conducting polymer, polypyrrole (Ppy), and a ferrocene catalyst were used to facilitate the growth process.
View Article and Find Full Text PDFNanomicro Lett
February 2023
Key Laboratory of Green Printing, CAS Research/Education Centre for Excellence in Molecular Sciences, Institute of Chemistry Chinese Academy of Sciences (ICCAS), Beijing, 100190, People's Republic of China.
Conducting polymers have achieved remarkable attentions owing to their exclusive characteristics, for instance, electrical conductivity, high ionic conductivity, visual transparency, and mechanical tractability. Surface and nanostructure engineering of conjugated conducting polymers offers an exceptional pathway to facilitate their implementation in a variety of scientific claims, comprising energy storage and production devices, flexible and wearable optoelectronic devices. A two-step tactic to assemble high-performance polypyrrole (PPy)-based microsupercapacitor (MSC) is utilized by transforming the current collectors to suppress structural pulverization and increase the adhesion of PPy, and then electrochemical co-deposition of PPy-CNT nanostructures on rGO@Au current collectors is performed.
View Article and Find Full Text PDFACS Omega
December 2022
Department of Materials Science and Engineering, National Taiwan University of Science and Technology, Taipei10607, Taiwan.
This work reports the preparation of graphene nanoplatelet (GNP)/multiwalled carbon nanotube (MWCNT)/polypyrrole (PPy) hybrid fillers via in situ chemical oxidative polymerization with the addition of a cationic surfactant, hexadecyltrimethylammonium bromide. These hybrid fillers were incorporated into polyurethane (PU) to prepare GNP/MWCNT/PPy/PU nanohybrids. The electrical conductivity of the nanohybrids was synergistically enhanced by the high conductivity of the hybrid fillers.
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