Four pairs of tautomers from rhizomes of and fruits of .

Nat Prod Res

State Key Laboratory of Bioactive Substance and Function of Natural Medicines, Institute of Materia Medica, Chinese Academy of Medical Sciences, Peking Union Medical College, Beijing, PR China.

Published: December 2023

A pair of new guaiane-type sesquiterpene tautomers () was isolated from rhizomes of . Meanwhile, three pairs of known compounds, including a pair of dihydroflavone glycoside tautomers (), a pair of 4-hydroxybenzoic acid ester glycoside tautomers (), as well as a pair of secoiridoid glycoside tautomers () were isolated from fruits of . Their structures were elucidated by extensive spectroscopic and computational methods. Furthermore, the tautomeric mechanisms were discussed.

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Source
http://dx.doi.org/10.1080/14786419.2022.2119969DOI Listing

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