Superhydrophobic microrobots that can swim efficiently and rapidly on water under the action of external stimuli have attracted significant research attention for various applications. However, most studies on superhydrophobic microrobots have focused on single-stimulus driving modes, which limit the motion and functional applications of microrobots in complex aquatic environments. Therefore, multistimuli-responsive superhydrophobic microrobots that are capable of drifting rapidly on water through light, magnetic, and chemical control were developed in this study. The stability and environmental adaptability of the microrobots were systematically investigated. The microrobots achieved programmable trajectory motion on water, particularly complex motions such as circular, spiral, and helical movements under the coupled influence of chemical and magnetic fields. Importantly, the motion and control of multimicrorobots can be realized by combining control methods. Under the action of light and magnetic field, multimicrorobots could realize cooperative movement and completed the transportation of cargo. Additionally, broad multifunctional applications of the microrobots were explored in terms of oil spill recovery and solution mix. This study provides a method for the preparation and development of superhydrophobic microrobots with multistimuli-responsive characteristics.
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http://dx.doi.org/10.1021/acsnano.2c05783 | DOI Listing |
ACS Nano
March 2024
School of Chemistry, Beihang University, Beijing 100191, China.
Dynamic manipulation of liquid metal (LM) droplets, a material combining metallicity and fluidity, has recently revealed tremendous potential in developing unconstrained microrobots. LM manipulating techniques based on magnetic fields, electric fields, chemical reactions, and ion concentration gradients in liquid environments have advanced considerably, but dynamic manipulation in air remains a challenge. Herein, a photoresponsive pyroelectric superhydrophobic (PPS) platform is proposed for noncontact, flexible, and controllable manipulation in the ambient atmosphere.
View Article and Find Full Text PDFSmall Methods
April 2024
Research Institute for Frontier Science, Beihang University, No. 37, Xueyuan Road, Haidian District, Beijing, 100191, P. R. China.
Natural fibers with robust water repellency play an important role in adapting organisms to various environments, which has inspired the development of artificial superhydrophobic fibrous materials with applications in self-cleaning, antifogging, water harvesting, heat exchanging, catalytic reactions, and microrobots. However, these highly textured surfaces (micro/nanotextured) suffer from frequent liquid penetration in high humidity and abrasion-induced destruction of the local environment. Herein, bioinspired superhydrophobic fibrous materials are reviewed from the perspective of the dimension scale of fibers.
View Article and Find Full Text PDFACS Nano
September 2022
State Key Laboratory of Robotics, Shenyang Institute of Automation, Chinese Academy of Sciences, Shenyang 110016, China.
Superhydrophobic microrobots that can swim efficiently and rapidly on water under the action of external stimuli have attracted significant research attention for various applications. However, most studies on superhydrophobic microrobots have focused on single-stimulus driving modes, which limit the motion and functional applications of microrobots in complex aquatic environments. Therefore, multistimuli-responsive superhydrophobic microrobots that are capable of drifting rapidly on water through light, magnetic, and chemical control were developed in this study.
View Article and Find Full Text PDFJ Colloid Interface Sci
December 2021
School of Chemistry and Chemical Engineering, Yangzhou University, Yangzhou, Jiangsu 225002, PR China; State Key Laboratory of Polymer Materials Engineering, Sichuan University, Chengdu, Sichuan 610065, PR China; Key Laboratory of Organosilicon Chemistry and Material Technology of Ministry of Education, Hangzhou Normal University, Hangzhou 311121, PR China. Electronic address:
Although some groundbreaking work has proved the feasibility of non-contact Marangoni propulsion generated by combination of the superhydrophobicity and photothermal effect, there are still challenges including the strong interfacial adhesion, multifunctional structural design and superior durability. In this paper, a simple two-step spraying method is used to prepare superhydrophobic and multi-functional fluorinated acidified carbon nanotubes (F-ACNTs)/FeO nanoparticles/polydimethylsiloxane (PDMS) coatings. The introduction of FeO nanoparticles and F-ACNTs not merely improve the surface roughness but also endow the coating with the outstanding magnetic property and photothermal conversion performance.
View Article and Find Full Text PDFACS Appl Mater Interfaces
January 2020
State Key Laboratory of High Performance Ceramics and Superfine Microstructure , Shanghai Institute of Ceramics, Chinese Academy of Sciences , Shanghai 200050 , P. R. China.
The direct transformation of external energy into mechanical work by the self-propelled motor inspires and promotes the development of miniaturized machines. Several strategies have been utilized to realize the self-driven motion, but in some cases multiple power sources are needed, and this would complicate the operation in diverse environments. In this regard, the dual-mode self-propelled system based on a single power source is highly desirable.
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