Distribution and transport of heavy metals in surface sediments of Chengbei Sea in the Bohai Sea.

It is of great significance to study the distribution characteristics and transport of heavy metals in complex sedimentary environments and areas with intensive human activities. This study analyzed sediment size, heavy metal contents (Cu, Zn, Cd, Cr, and Pb), organic carbon content, and sulfide content in surface sediments collected from 27 sites in Chengbei Sea. The main controlling factors of the distribution and transport of heavy metals were discussed from the perspective of sediment dynamics. The concentrations of Cu, Zn, Cd, Cr, and Pb in surface sediments were 7.9-20.5 mg/kg, 33.8-94.6 mg/kg, 0.08-0.26 mg/kg, 6.3-62.3 mg/kg, and 3-13.4 mg/kg, respectively. According to the geoaccumulation index, the study area was not polluted by the heavy metals, except for Cd, which did not pollute only areas with relatively coarse-grained sediments. Combining the results of correlation analysis, tidal residual current analysis, sediment transport trend analysis, and principal component analysis confirmed that Cu, Zn, and Cd originate from natural sources, and their distribution characteristics are mainly controlled by the grain size of surface sediments. Cr and Pb could be attributed to human activities, such as oil exploration, and their distribution characteristics were affected by sediment transport and tidal residual current. Zonation of the sedimentary dynamic environment also provided reference for the relationship between the distribution of heavy metals in surface sediments and sedimentary environments.