Switchable SO capture and CF migration of enol triflates with peroxyl compounds under iron catalysis are presented. By regulating the structure of peroxides, a variety of keto-functionalized dialkyl sulfones and α-trifluoromethyl ketones were selectively synthesized in good yields under mild conditions.
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| http://dx.doi.org/10.1021/acs.orglett.2c02663 | DOI Listing |
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