An electrooxidation strategy mediated by reactive oxygen species is proposed to realize the transformation of styrene to benzaldehyde on a Pt anode, with a high selectivity of 89% and faradaic efficiency of 28.8%. Isotopic labelling, electron paramagnetic resonance and radical scavenging experiments revealed that OH˙ and O˙ species, formed anodic water oxidation, play a crucial role in the selective formation of benzaldehyde.

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http://dx.doi.org/10.1039/d2cc02618jDOI Listing

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