Anti-oil-fouling Au/BiOCl coating for visible light-driven photocatalytic inactivation of bacteria.

In this work, gold/bismuth oxychloride (Au/BiOCl) nanocomposites with different morphologies were successfully prepared by simple solvothermal method and sodium borohydride reduction method, which exhibited significantly efficient visible-light-driven photocatalytic disinfection for Staphylococcus aureus (S.aureus). Particularly, the flower-like Au/BiOCl nanocomposite showed the highest photocatalytic bactericidal performance among the prepared Au/BiOCl samples. The radical trapping experiments revealed that the hole was the main reactive species responsible for the inactivation of S.aureus over Au/BiOCl composite. The enhanced photocatalytic bactericidal effect could be attributed to the enhanced adsorption intensity of visible light that originated from the surface plasmon resonance (SPR) effect of Au, rapid transfer and space transport of hot electrons caused by the hierarchical structure of BiOCl layered compound. Furthermore, the Au/BiOCl coating prepared on stainless steel wire mesh via in-situ synthesis method exhibited excellent superhydrophilic/underwater superoleophobic performance, which endowed the coating with anti-oil-fouling in water. More importantly, compared with Au/BiOCl powder catalyst, the prepared Au/BiOCl coating with anti-oil-fouling also possessed high photocatalytic bactericidal activity and stable recycling performance.