We consider the motion of a self-propelled object of rectangular shape inside a circular water chamber. The mathematical model of self-motion includes equations for the orientation and location of the rectangle and reaction-diffusion equation with an effective diffusion coefficient for the time evolution of the surface concentration of active molecules. Numerical simulations of motion were performed for different values of the ratio between the supply rate and the evaporation rate of active molecules. Treating = / as a control parameter, we found the critical behavior in variables characterizing the trajectory and identified different types of motion. If the value of is small, the rectangle rests at the chamber center. For larger , a reciprocal motion during which the rectangle passes through the center is observed. At yet higher supply rates, the star-polygonal motion appears, and the trajectory remains at a distance from the chamber center. In the experiments with a rectangle made of camphor-camphene-polypropylene plastic moving in a Petri dish, we observed the transition from the star-polygonal motion to the reciprocal motion in time. This transition can be understood on the basis of the developed model if we assume that the supply rate decreases in time.

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http://dx.doi.org/10.1039/d2cp02456jDOI Listing

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