Synthesis and structure of hexa-aqua-cobalt bis-(2-methyl-1-imidazol-3-ium) tetra-aqua-bis-(benzene-1,3,5-tri-carboxyl-ato-κ)cobalt.

Acta Crystallogr E Crystallogr Commun

Deutsches Elektronen-Synchrotron DESY, Notkestr. 85, 22607 Hamburg, Germany.

Published: August 2022

The title compound, (CHN)[Co(HO)][Co(CHO)(HO)] (), was synthesized from cobalt(II) chloride, 1,3,5-benzene tri-carb-oxy-lic acid (Hbtc) and 2-methyl-imidazole (H-2mIm) under ambient conditions. The structure of is here reported and compared with the parent complex hexa-aqua-cobalt bis-(1-imidazol-3-ium) tetra-aqua-bis-(benzene-1,3,5-tri-carboxyl-ato)cobalt ().

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Source
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC9361360PMC
http://dx.doi.org/10.1107/S2056989022007046DOI Listing

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